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9-Borabicyclo[3.3.1]nonane, 0.5M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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Metalloheterocyclic compounds

Molecular Weight (g/mol)	122.02
CAS Min %	92.49
Chemical Name or Material	9-Borabicyclo[3.3.1]nonane
SMILES	[B]1C2CCCC1CCC2
InChI Key	AMKGKYQBASDDJB-UHFFFAOYSA-N
Density	0.8840g/mL
PubChem CID	6327450
Fieser	02,31; 03,24; 04,41; 05,46; 06,62; 07,29; 08,47; 09,57; 10,48; 11,68; 13,92; 14,52; 15,43; 17,49; 01,732; 04,356
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture
MDL Number	MFCD00074742
Health Hazard 2	GHS H Statement In contact with water releases flammable gases. Highly flammable liquid and vapor. Causes severe skin burns and eye damage. May cause respiratory irritation. Suspected of causing cancer. May form explo
Solubility Information	Solubility in water: reacts
Flash Point	−17°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	9-borabicyclo 3.3.1 nonane,9-borabicyclo 3.3.1 nonan,9-borabicyclo 3,3,1 nonane,9$l^ 2-borabicyclo 3.3.1 nonane,1s,5s-9-borabicyclo 3.3.1 nonane,monomer; 21205-91-4 dimer,9-borabicyclo 3.3.1 nonane,9-bbn,intetrahydrofuran
IUPAC Name	9$l^{2}-borabicyclo[3.3.1]nonane
Molecular Formula	C₈H₁₅B
EINECS Number	206-000-9
Formula Weight	122.02
Specific Gravity	0.884
CAS Max %	93.86

hydrogen chloride, 4N solution in 1,4-dioxane, AcroSeal™, Thermo Scientific Chemicals

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General Chemistry Solutions

Linear Formula	HCl
Molecular Weight (g/mol)	36.46
ChEBI	CHEBI:17883
InChI Key	VEXZGXHMUGYJMC-UHFFFAOYSA-N
Density	1.0500g/mL
PubChem CID	313
Name Note	4N solution in 1, 4-dioxane
Formula Weight	36.45
Color	Colorless to White
Physical Form	Crystals or Crystalline Powder
Chemical Name or Material	Hydrochloric acid
SMILES	Cl
Merck Index	14, 4794
Concentration	3.95 to 4.40N
CAS	123-91-1
Health Hazard 3	GHS P Statement: Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Avoid breathing dust/fume/gas/mist/vapors/spray. Keep container tightly closed. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment. WARNING: The inform
MDL Number	MFCD00011324 MFCD00792839
Health Hazard 2	GHS H Statement: Causes severe skin burns and eye damage. Suspected of causing cancer. Toxic if inhaled. Highly flammable liquid and vapor. May form explosive peroxides. Repeated exposure may cause skin dryness or cracking.
Flash Point	17°C
Packaging	AcroSeal™ Glass Bottle
Solubility Information	Solubility in water: soluble. Other solubilities: soluble in most organic solvents
Health Hazard 1	Danger
Synonym	hydrochloric acid,hydrogen chloride,muriatic acid,chlorohydric acid,acide chlorhydrique,chlorwasserstoff,spirits of salt,hydrogen chloride hcl,anhydrous hydrochloric acid,chloorwaterstof
IUPAC Name	hydrogen chloride
Molecular Formula	ClH
Specific Gravity	1.05

Tetrabutylammonium fluoride, 1M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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Ammonium Salts

Linear Formula	[CH₃(CH₂)₃]₄NF
Molecular Weight (g/mol)	261.47
ChEBI	CHEBI:51990
Color	Brown to Green
Physical Form	Solution
SMILES	[F-].CCCC[N+](CCCC)(CCCC)CCCC
Merck Index	15,9332
InChI Key	FPGGTKZVZWFYPV-UHFFFAOYSA-M
Density	0.8870g/mL
PubChem CID	2724141
Concentration or Composition (by Analyte or Components)	0.90 to 1.10M
CAS	7732-18-5
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/protective clothing/eye p
MDL Number	MFCD00011747
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. Suspected of causing cancer. May cause respiratory irritation. Highly flammable liquid and vapor. May form explosive peroxides. May cause drowsiness or dizzines
Flash Point	−17°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	tetrabutylammonium fluoride,tbaf,tetrabutylazanium fluoride,tetrabutyl ammonium fluoride,tetra-n-butylammonium fluoride,tetrabutylamine, fluoride,n,n,n-tributylbutan-1-aminium fluoride,1-butanaminium, n,n,n-tributyl-, fluoride,n,n,n-tributyl-1-butanaminium fluoride,1-butanaminium, n,n,n-tributyl-, fluoride 1:1
IUPAC Name	tetrabutylazanium;fluoride
Molecular Formula	C16H36FN
EINECS Number	207-057-2
Formula Weight	261.46
Specific Gravity	0.887

Isopropylmagnesium chloride, 2.0M solution in THF, AcroSeal™, Thermo Scientific Chemicals

CAS: 1068-55-9 Molecular Formula: C3H7ClMg Molecular Weight (g/mol): 102.84 MDL Number: MFCD00000466 InChI Key: GPIBKUJXKCEZOH-UHFFFAOYSA-M Synonym: isopropylmagnesium chloride,magnesium, chloro 1-methylethyl,chloro 1-methylethyl magnesium,i-prmgcl,isopropylmagnesiumchloride,chloro isopropyl magnesium,isopropyl magnesium chloride,isopropylmagnesium chloride solution,iprmgcl,ipr-mgcl PubChem CID: 101955 SMILES: CC(C)[Mg]Cl

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General Chemistry Solutions

PubChem CID	101955
CAS	1068-55-9
Molecular Weight (g/mol)	102.84
MDL Number	MFCD00000466
SMILES	CC(C)[Mg]Cl
Synonym	isopropylmagnesium chloride,magnesium, chloro 1-methylethyl,chloro 1-methylethyl magnesium,i-prmgcl,isopropylmagnesiumchloride,chloro isopropyl magnesium,isopropyl magnesium chloride,isopropylmagnesium chloride solution,iprmgcl,ipr-mgcl
InChI Key	GPIBKUJXKCEZOH-UHFFFAOYSA-M
Molecular Formula	C3H7ClMg

Borane-tetrahydrofuran complex, 1M solution in THF, Stabilized, AcroSeal™, Thermo Scientific Chemicals

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General Chemistry Solutions

Molecular Weight (g/mol)	85.94
InChI Key	RMCYTHFAWCWRFA-UHFFFAOYSA-N
Density	0.8760g/mL
Treatment(s)	Stabilized
PubChem CID	11062302
Name Note	1M solution in tetrahydrofuran, stabilized
Fieser	01,199; 02,106; 03,76; 04,124; 05,184; 06,161; 07,89; 12,65; 17,101
Formula Weight	85.94
Color	Colorless
Physical Form	Liquid
Chemical Name or Material	Borane-tetrahydrofuran complex
SMILES	B.C1CCOC1
Merck Index	15, 1336
Concentration	0.96 to 1.08M
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00012429
Health Hazard 2	GHS H Statement May cause respiratory irritation. Causes serious eye damage. In contact with water releases flammable gases which may ignite spontaneously. Causes skin irritation. Harmful if swallowed. Highly flammable liquid and vapour. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides. May cause drowsiness or dizziness.
Flash Point	−22°C
Packaging	AcroSeal™ Glass bottle
Solubility Information	Solubility in water: reacts.
Health Hazard 1	Danger
Synonym	borane-tetrahydrofuran complex,tetrahydrofuran borane,bh3.thf,borane tetrahydrofuran complex solution,borane-d3-thf complex solution,borane-tetrahydrofuran,unii-5ear4err1l,oxolane borane,boron; oxolane,borane thf
TSCA	TSCA
IUPAC Name	oxolane borane
Molecular Formula	C4H11BO
EINECS Number	237-881-8
Specific Gravity	0.876

Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

CAS: 4111-54-0 Molecular Formula: C6H14LiN Molecular Weight (g/mol): 107.125 MDL Number: MFCD00064449 InChI Key: ZCSHNCUQKCANBX-UHFFFAOYSA-N Synonym: lithium diisopropylamide,unii-ol028kiw1i,lithium di-isopropylamide,lithium diisopropyl amide,2-propanamine, n-1-methylethyl-, lithium salt,ol028kiw1i,lithium di propan-2-yl azanide,2-propanamine, n-1-methylethyl-, lithium salt 1:1,lithium n,n-diisopropylamide,ipr2nli PubChem CID: 2724682 IUPAC Name: lithium;di(propan-2-yl)azanide SMILES: [Li+].CC(C)[N-]C(C)C

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General Chemistry Solutions

PubChem CID	2724682
CAS	4111-54-0
Molecular Weight (g/mol)	107.125
MDL Number	MFCD00064449
SMILES	[Li+].CC(C)[N-]C(C)C
Synonym	lithium diisopropylamide,unii-ol028kiw1i,lithium di-isopropylamide,lithium diisopropyl amide,2-propanamine, n-1-methylethyl-, lithium salt,ol028kiw1i,lithium di propan-2-yl azanide,2-propanamine, n-1-methylethyl-, lithium salt 1:1,lithium n,n-diisopropylamide,ipr2nli
IUPAC Name	lithium;di(propan-2-yl)azanide
InChI Key	ZCSHNCUQKCANBX-UHFFFAOYSA-N
Molecular Formula	C6H14LiN

n-Butyllithium, 2.5M solution in hexanes, AcroSeal™, Thermo Scientific Chemicals

CAS: 109-72-8,110-54-3 Molecular Formula: C4H9Li Molecular Weight (g/mol): 64.06 MDL Number: MFCD00009414 InChI Key: MZRVEZGGRBJDDB-UHFFFAOYSA-N Synonym: n-butyllithium,lithium, butyl,butyllithium,butyl lithium,n-butyl lithium,lithium butane,n-buli,buli,libu,unii-09w9a6b8zc PubChem CID: 61028 SMILES: [Li]CCCC

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Organic lithium salts

PubChem CID	61028
CAS	109-72-8,110-54-3
Molecular Weight (g/mol)	64.06
MDL Number	MFCD00009414
SMILES	[Li]CCCC
Synonym	n-butyllithium,lithium, butyl,butyllithium,butyl lithium,n-butyl lithium,lithium butane,n-buli,buli,libu,unii-09w9a6b8zc
InChI Key	MZRVEZGGRBJDDB-UHFFFAOYSA-N
Molecular Formula	C4H9Li

Methylmagnesium bromide, 3M solution in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

CAS: 75-16-1 Molecular Formula: CH3BrMg Molecular Weight (g/mol): 119.24 MDL Number: MFCD00000041 InChI Key: AVFUHBJCUUTGCD-UHFFFAOYSA-M Synonym: methylmagnesium bromide,grignard reagent,magnesium, bromomethyl,magnesium, bromomethyl,bromo methyl magnesium,unii-22cw9773df,memgbr,memgbr,ch3mgbr,ch3mgbr,methylmagnesiumbromide PubChem CID: 6349 SMILES: C[Mg]Br

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General Chemistry Solutions

PubChem CID	6349
CAS	75-16-1
Molecular Weight (g/mol)	119.24
MDL Number	MFCD00000041
SMILES	C[Mg]Br
Synonym	methylmagnesium bromide,grignard reagent,magnesium, bromomethyl,magnesium, bromomethyl,bromo methyl magnesium,unii-22cw9773df,memgbr,memgbr,ch3mgbr,ch3mgbr,methylmagnesiumbromide
InChI Key	AVFUHBJCUUTGCD-UHFFFAOYSA-M
Molecular Formula	CH3BrMg

Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal™, Thermo Scientific Chemicals

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Organoaluminum

Linear Formula	[(CH₃)₂CHCH₂]₂AlH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.7010g/mL
Name Note	1M Solution in Hexane
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	110-54-3
Health Hazard 3	GHS P Statement IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective g
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement May be fatal if swallowed and enters airways. Toxic to aquatic life with long lasting effects. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. May cause damage to organs through p
Solubility Information	Solubility in water: reacts
Flash Point	−23°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.701
Melting Point	-70.0°C

Diisobutylaluminium hydride, 1.2M (20 wt%) solution in toluene, AcroSeal™, Thermo Scientific Chemicals

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Organoaluminum

Boiling Point	110.0°C
Linear Formula	[(CH₃)₂CHCH₂]₂AIH
Molecular Weight (g/mol)	142.22
Physical Form	Solution
Chemical Name or Material	Diisobutylaluminium hydride
Merck Index	15, 3212
Density	0.8480g/mL
Fieser	01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
CAS	108-88-3
Health Hazard 3	GHS P Statement IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsi
MDL Number	MFCD00008928
Health Hazard 2	GHS H Statement Causes severe skin burns and eye damage. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. Suspected of damaging the unborn child. May cause dro
Solubility Information	Solubility in water: reacts violently. Other solubilities: miscible with saturated aliphatic and aromatic,hydrocarbons
Flash Point	4°C
Health Hazard 1	GHS Signal Word: Danger
Synonym	DIBAL-H
Beilstein	04, IV, 4400
Molecular Formula	C₈H₁₉Al
EINECS Number	214-729-9
Formula Weight	142.22
Specific Gravity	0.848

Tetraethyl orthosilicate, 98%, AcroSeal™, Thermo Scientific Chemicals

CAS: 78-10-4 Molecular Formula: C₈H₂₀O₄Si Molecular Weight (g/mol): 208.33 InChI Key: BOTDANWDWHJENH-UHFFFAOYSA-N Synonym: tetraethyl orthosilicate,tetraethoxysilane,teos,ethyl silicate,silicon ethoxide,silicon tetraethoxide,silane, tetraethoxy,dynasil a,tetraethoxysilicon,ethyl orthosilicate PubChem CID: 6517 IUPAC Name: tetraethyl silicate SMILES: CCO[Si](OCC)(OCC)OCC

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Organo-Metalloid Compounds

PubChem CID	6517
CAS	78-10-4
Molecular Weight (g/mol)	208.33
SMILES	CCO[Si](OCC)(OCC)OCC
Synonym	tetraethyl orthosilicate,tetraethoxysilane,teos,ethyl silicate,silicon ethoxide,silicon tetraethoxide,silane, tetraethoxy,dynasil a,tetraethoxysilicon,ethyl orthosilicate
IUPAC Name	tetraethyl silicate
InChI Key	BOTDANWDWHJENH-UHFFFAOYSA-N
Molecular Formula	C₈H₂₀O₄Si

Methyllithium, 1.6M sol. in diethyl ether (± 5% w/v), AcroSeal™, Thermo Scientific Chemicals

CAS: 917-54-4 Molecular Formula: CH3Li Molecular Weight (g/mol): 21.98 MDL Number: MFCD00008253 InChI Key: DVSDBMFJEQPWNO-UHFFFAOYSA-N Synonym: methyllithium,lithium, methyl,methyl lithium,lithium methanide,meli,lithium methyl,lithium carbanide,lithium methide,methllithium,methyllithum PubChem CID: 2724049 SMILES: [Li]C

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General Chemistry Solutions

PubChem CID	2724049
CAS	917-54-4
Molecular Weight (g/mol)	21.98
MDL Number	MFCD00008253
SMILES	[Li]C
Synonym	methyllithium,lithium, methyl,methyl lithium,lithium methanide,meli,lithium methyl,lithium carbanide,lithium methide,methllithium,methyllithum
InChI Key	DVSDBMFJEQPWNO-UHFFFAOYSA-N
Molecular Formula	CH3Li

Lithium aluminum hydride, 1M solution in THF, AcroSeal™, Thermo Scientific Chemicals

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General Chemistry Solutions

Linear Formula	LiAlH₄
Molecular Weight (g/mol)	37.95
Color	Gray
Physical Form	Turbid Solution
Chemical Name or Material	Lithium Aluminum hydride
SMILES	[Li+].[AlH4-]
Merck Index	15, 344
InChI Key	OCZDCIYGECBNKL-UHFFFAOYSA-N
Density	0.9000g/mL
PubChem CID	21226445
Percent Purity	3.9 to 4.5% (as LiAlH4)
Fieser	01,581; 02,242; 03,176; 04,291; 05,382; 06,325; 07,196; 08,286; 09,274; 10,236; 11,289; 12,272; 13,61; 14,190; 15,184; 16,133; 17,162
CAS	109-99-9
Health Hazard 3	GHS P Statement Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
MDL Number	MFCD00011075
Health Hazard 2	GHS H Statement May cause respiratory irritation. Causes skin irritation. Causes serious eye damage. Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. May form explosive peroxides. Suspected of causing cancer. Harmful if swallowed. May cause drowsiness or dizziness.
Flash Point	−17°C
Solubility Information	Solubility in water: vigorous reaction.
Health Hazard 1	Danger
Synonym	lithium aluminum hydride,lithium aluminum hydride,aluminum lithium hydride,lithiumaluminiumhydride,aluminum iii lithium hydride,lithium alanate,lithium aluminum tetrahydride,lithiumaluminiumhydrid,litiumaluminum hydride,lithim aluminum hydride
IUPAC Name	aluminum;lithium;hydride
Molecular Formula	AlH4Li
Formula Weight	37.95
Specific Gravity	0.9

n-Butyllithium, 1.6M solution in hexanes, AcroSeal™, Thermo Scientific Chemicals

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Organic lithium salts

PubChem CID	61028
CAS	109-72-8,110-54-3
Molecular Weight (g/mol)	64.06
MDL Number	MFCD00009414
SMILES	[Li]CCCC
Synonym	n-butyllithium,lithium, butyl,butyllithium,butyl lithium,n-butyl lithium,lithium butane,n-buli,buli,libu,unii-09w9a6b8zc
InChI Key	MZRVEZGGRBJDDB-UHFFFAOYSA-N
Molecular Formula	C4H9Li

Triisobutylaluminium, 1.1M solution in toluene, AcroSeal™, Thermo Scientific Chemicals

CAS: 100-99-2 Molecular Formula: C12H27Al Molecular Weight (g/mol): 198.33 MDL Number: MFCD00008929 InChI Key: MCULRUJILOGHCJ-UHFFFAOYSA-N Synonym: triisobutylaluminum,triisobutylaluminium,aluminum, tris 2-methylpropyl,tibal,triisobutylalane,triisobutyl aluminum,aluminum, triisobutyl,tris isobutyl alane,tris isobutyl aluminum,unii-09p2thv2x4 PubChem CID: 16682931 IUPAC Name: tris(2-methylpropyl)alumane SMILES: CC(C)C[Al](CC(C)C)CC(C)C

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General Chemistry Solutions

PubChem CID	16682931
CAS	100-99-2
Molecular Weight (g/mol)	198.33
MDL Number	MFCD00008929
SMILES	CC(C)C[Al](CC(C)C)CC(C)C
Synonym	triisobutylaluminum,triisobutylaluminium,aluminum, tris 2-methylpropyl,tibal,triisobutylalane,triisobutyl aluminum,aluminum, triisobutyl,tris isobutyl alane,tris isobutyl aluminum,unii-09p2thv2x4
IUPAC Name	tris(2-methylpropyl)alumane
InChI Key	MCULRUJILOGHCJ-UHFFFAOYSA-N
Molecular Formula	C12H27Al

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