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  6. tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals

tert-Butyldichlorophosphine, 98%, Thermo Scientific Chemicals

Catalog Number AAH2736018
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Quantity:
1 g
10 g
50 g
25979-07-1
C4H9Cl2P
158.99
MFCD00013615
NMJASRUOIRRDSX-UHFFFAOYSA-N
tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride
117690
tert-butyl(dichloro)phosphane
CC(C)(C)P(Cl)Cl
25979-07-1
C4H9Cl2P
158.99
MFCD00013615
NMJASRUOIRRDSX-UHFFFAOYSA-N
tert-butyldichlorophosphine, t-butyldichlorophosphine, tert-c4h9pcl2, tert-butyl dichloro phosphane, phosphonous dichloride, 1,1-dimethylethyl, snpladsptpdwuup@, pubchem6471, acmc-1cmec, tert-butyl dichloro phosphine, tert-butylphosphine dichloride
117690
tert-butyl(dichloro)phosphane
CC(C)(C)P(Cl)Cl

Description

Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.

Notes
Air & Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, strong bases, air, water and moisture.
TRUSTED_SUSTAINABILITY
Melting Point 44°C to 49°C
Linear Formula (CH3)3CPCl2
Quantity 50 g
UN Number UN3261
Sensitivity Air and moisture sensitive
Solubility Information Reacts with water. Soluble in n-Pentane,n-Hexane,Ether,Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
Formula Weight 159
Percent Purity 98%
Chemical Name or Material tert-Butyldichlorophosphine

Safety and Handling

Hazard Category H314-H335
Hazard Statement GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Precautionary Statement P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
DOTInformation Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
EINECSNumber 247-386-9
TSCA No
Recommended Storage Ambient temperatures; Store under Nitrogen
SDS

RUO – Research Use Only

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