tert-Butyl hydroperoxide, 70% aq. soln., Thermo Scientific Chemicals

Description

tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.

Specifications

• Melting Point: -3°C
• Density: 0.937
• Boiling Point: 96°C (decomposition)
• Flash Point: 43°C (109°F)
• Assay Percent Range: 70% Aqueous Solution
• Refractive Index: 1.387
• Linear Formula: (CH₃)₃COOH
• Quantity: 2500 mL
• UN Number: UN3109
• Beilstein: 1098280
• Merck Index: 14,1570
• Solubility Information: Miscible with water and diethyl ether.
• Formula Weight: 90.12
• Concentration or Composition (by Analyte or Components): 70% aq. soln.
• Chemical Name or Material: tert-Butyl hydroperoxide

Safety and Handling

Hazard Category	H226-H242-H302-H311-H314-H317-H330-H335-H341
Hazard Statement	GHS H Statement H300-H310-H330-H314-H226-H242 Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Flammable liquid and vapour. Heating may cause a fire.
Precautionary Statement	P201-P202-P210-P220-P233-P234-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P272-P280g-P281-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P37
DOTInformation	Hazard Class: 5.2
EINECSNumber	200-915-7
RTECSNumber	EQ4900000
TSCA	Yes
Recommended Storage	Keep cold

SDS

RUO – Research Use Only