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Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene., Thermo Scientific Chemicals
Description
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.
Solubility
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.
Specifications
| Density | 1.02 |
| Flash Point | 4°C (39°F) |
| Linear Formula | NaAlH2(OCH2CH2OCH3)2 |
| Quantity | 50 g |
| UN Number | UN3399 |
| Sensitivity | Moisture sensitive |
| Merck Index | 14,8565 |
| Solubility Information | Miscible with aromatic hydrocarbons,ether,tetrahydrofuran,dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons. |
| Formula Weight | 202.16 |
| Chemical Name or Material | Sodium bis(2-methoxyethoxy)aluminum hydride |
Safety and Handling
| Hazard Category | H225-H304-H314-H318-H361-H373-X |
| Hazard Statement | GHS H Statement H225-H260-H304-H361-H373-H314-H332-H336 Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. Harmful if inhaled. May cause drowsiness or dizziness. |
| Precautionary Statement | P201-P202-P210-P233-P240-P241-P242-P243-P261-P262-P264b-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P331-P363-P372-P374-P380-P501c |
| DOTInformation | Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE |
| EINECSNumber | 245-178-2 |
| TSCA | Yes |
| Recommended Storage | Ambient temperatures |
RUO – Research Use Only
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