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(N,N-Dimethyl)methyleneammonium iodide, 97%, Thermo Scientific Chemicals

Catalog Number AAA1514609
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Quantity:
10 g
50 g
250 g
33797-51-2
C3H8IN
185.008
MFCD00011810
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide
2724133
dimethyl(methylidene)azanium;iodide
C[N+](=C)C.[I-]
33797-51-2
C3H8IN
185.008
MFCD00011810
VVDUZZGYBOWDSQ-UHFFFAOYSA-M
eschenmoser's salt, n,n-dimethylmethyleneiminium iodide, n-methyl-n-methylenemethanaminium iodide, dimethyl methylidene azanium iodide, n,n-dimethyl methyleneammonium iodide, dimethyl methylene ammonium iodide, methanaminium, n-methyl-n-methylene-, iodide, eschenmoser inverted exclamation mark s salt, eschenmoser salt, dimethyl methylene ammounium iodide
2724133
dimethyl(methylidene)azanium;iodide
C[N+](=C)C.[I-]

(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH2N(CH3)2. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.

Solubility
Soluble in dimethylformamide. Partially soluble in acetonitrile, tetrahydrofuran and dichloromethane.

Notes
Moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place.
TRUSTED_SUSTAINABILITY
Melting Point ∼240°C (decomposition)
Quantity 10 g
Beilstein 3594966
Sensitivity Light and moisture sensitive
Merck Index 14,3251
Solubility Information Soluble in dimethylformamide. Partially soluble in acetonitrile,tetrahydrofuran and dichloromethane.
Formula Weight 185.01
Percent Purity 97%
Chemical Name or Material (N,N-Dimethyl)methyleneammonium iodide
Hazard Category H315-H319-H335
Hazard Statement GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
EINECSNumber 251-680-2
TSCA No
Recommended Storage Keep cold

RUO – Research Use Only

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