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Chlorobis(2-methoxyphenyl)phosphine, 98+%, Thermo Scientific Chemicals

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Quantity:
1 g
5 g
263369-88-6
C18H17ClO2P-
331.756
MFCD08064037
WVGQIZOJKMMSSK-UHFFFAOYSA-N
bis 2-methoxyphenyl chlorphosphine, acmc-20alnz, phosphinous chloride,p,p-bis 2-methoxyphenyl
57371085
COC1=CC=CC=C1C2=C(P[Cl-]C=C2)C3=CC=CC=C3OC
263369-88-6
C18H17ClO2P-
331.756
MFCD08064037
WVGQIZOJKMMSSK-UHFFFAOYSA-N
bis 2-methoxyphenyl chlorphosphine, acmc-20alnz, phosphinous chloride,p,p-bis 2-methoxyphenyl
57371085
COC1=CC=CC=C1C2=C(P[Cl-]C=C2)C3=CC=CC=C3OC

Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.
Melting Point 111°C to 114°C
Quantity 5 g
UN Number UN3261
Sensitivity Air and moisture sensitive
Solubility Information Reacts with water.
Formula Weight 280.69
Percent Purity ≥98%
Chemical Name or Material Chlorobis(2-methoxyphenyl)phosphine

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber : 000-000-0

TSCA : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

RUO – Research Use Only