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  7. 3-Bromopyridine, 98+%, Thermo Scientific Chemicals

3-Bromopyridine, 98+%, Thermo Scientific Chemicals

Catalog Number AAA1289436
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Quantity:
25 g
100 g
500 g
626-55-1
C5H4BrN
158.00
MFCD00006373
NYPYPOZNGOXYSU-UHFFFAOYSA-N
3-pyridyl bromide, pyridine, 3-bromo, 3-bromo pyridine, 3-bromo-pyridine, 5-bromopyridine, unii-xmn8h2xe9h, 5-bromo pyridine, xmn8h2xe9h, 3-pyridylbromide, 3-bromopryidine
12286
CHEBI:51575
3-bromopyridine
BrC1=CC=CN=C1
626-55-1
C5H4BrN
158.00
MFCD00006373
NYPYPOZNGOXYSU-UHFFFAOYSA-N
3-pyridyl bromide, pyridine, 3-bromo, 3-bromo pyridine, 3-bromo-pyridine, 5-bromopyridine, unii-xmn8h2xe9h, 5-bromo pyridine, xmn8h2xe9h, 3-pyridylbromide, 3-bromopryidine
12286
CHEBI:51575
3-bromopyridine
BrC1=CC=CN=C1

Description

3-Bromopyridine undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, involved in formation of the Grignard by Mg exchange with i-PrMgCl and in transmetallation of the lithiated derivative with zinc chloride followed by treatment with an electrophile as a route to 4-substituted 3-bromopyridines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Bromopyridine undergoes lithiation with LDA at low temperatures in the 4-position: Heterocycles, involved in formation of the Grignard by Mg exchange with i-PrMgCl and in transmetallation of the lithiated derivative with zinc chloride followed by treatment with an electrophile as a route to 4-substituted 3-bromopyridines.

Solubility
Soluble in water (31 g/L at 20°C).

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong acids.
TRUSTED_SUSTAINABILITY
Melting Point -27°C
Density 1.617
Boiling Point 172°C to 174°C
Flash Point 72°C (181°F)
Odor Characteristic
Refractive Index 1.57
Quantity 500 g
UN Number UN2810
Beilstein 105880
Solubility Information Soluble in water (31g/L at 20°C).
Formula Weight 158
Percent Purity ≥98%
Chemical Name or Material 3-Bromopyridine
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Safety and Handling

Hazard Category H226-H301+H311+H331-H315-H319-H335
Hazard Statement GHS H Statement
H311-H227-H302-H332-H315-H319-H335
Toxic in contact with skin.
Combustible liquid.
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P311-P312-P330-P332+P313-P363-P370+P378q-P501c
DOTInformation Hazard Class: 6.1; Packaging Group: II
EINECSNumber 210-952-0
TSCA Yes
Recommended Storage Ambient temperatures
SDS

RUO – Research Use Only

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