Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals

Description

Grignard reagent

Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 100-58-3
• Molecular Formula: C6H5BrMg
• Molecular Weight (g/mol): 181.32
• MDL Number: MFCD00000038
• InChI Key: ANRQGKOBLBYXFM-UHFFFAOYSA-M
• Synonym: phenylmagnesium bromide, bromophenylmagnesium, magnesium, bromophenyl, phmgbr, phenylmagnesiumbromide, bromo phenyl magnesium, phenyl magnesium bromide, phenylmagnesium bromide solution, 3.0 m in diethyl ether, bromomagnesiobenzene, phenyhnagnesium bromide, grignard reagent
• PubChem CID: 66852
• SMILES: Br[Mg]C1=CC=CC=C1

• Color: Yellow to Brown
• Density: 1.14 g/mL
• Odor: Ether-like
• Quantity: 100 mL
• UN Number: UN3399
• Sensitivity: Air, light, and moisture sensitive; May form a Precipitate
• Solubility Information: Miscible with terahydrofuran.
• IUPAC Name: bromo(phenyl)magnesium
• Formula Weight: 181.31
• Concentration or Composition (by Analyte or Components): 3M in ether
• Physical Form: Liquid
• Chemical Name or Material: Phenylmagnesium bromide

Safety and Handling

Hazard Category	H224-H314-H335-H336
Hazard Statement	GHS H Statement H224-H261-H314-H336 Extremely flammable liquid and vapor. In contact with water releases flammable gas. Causes severe skin burns and eye damage. May cause drowsiness or dizziness.
Precautionary Statement	P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
DOTInformation	Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA	Yes
Recommended Storage	Ambient temperatures; Store under Argon

SDS

RUO – Research Use Only